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Structural and electric-optical properties of zinc phthalocyanine evaporated thin films : Temperature and thickness effects

It is known that the molecular architecture plays a fundamental role in the electrical and optical properties of materials processed in the form of thin films. Here, zinc phthalocyanine (ZnPc) thin films were fabricated through the vacuum thermal evaporation technique (PVD, physical vapor deposition) up to 50 nm thickness with the objective of determining their molecular architecture and some elec

Layer-by-layer technique as a new approach to produce nanostructured films containing phospholipids as transducers in sensing applications

Phospholipids are widely used as mimetic systems to exploit interactions involving biological membranes and pharmacological drugs. In this work, the layer-by-layer (LbL) technique was used as a new approach to produce multilayered thin films containing biological phospholipids applied as transducers onto Pt interdigitated electrodes forming sensing units of an electronic tongue system. Low concent

Exploiting distinct molecular architectures of ultrathin films made with iron phthalocyanine for sensing

The possibility of generating distinct film properties from the same material is crucial for a number of applications, which can only be achieved by controlling the molecular architecture. In this paper we demonstrate as a proof-of-principle that ultrathin films produced from iron phthalocyanine (FePc) may be used to detect trace amounts of copper ions in water, where advantage was taken of the cr

Sensor array made with nanostructured films to detect a phenothiazine compound

The detection of trace amounts of phenothiazines with fast, direct methods is important for medical applications and the pharmaceutical industry. In this paper we explore the concept of an electronic tongue to detect methylene blue (MB), with a sensor array comprising 6 units. These units were a bare Pt electrode, and Pt electrodes coated with 1 -layer LB films of dipalmitoyl phosphatidylcholine (

Molecular and morphological characterization of bis benzimidazo perylene films and surface-enhanced phenomena

Thin solid films of bis benzimidazo perylene (AzoPTCD) were fabricated using physical vapor deposition (PVD) technique. Thermal stability and integrity of the AzoPTCD PVD films during the fabrication (∼400 °C at 10 -6 Torr) were monitored by Raman scattering. Complementary thermogravimetric results showed that thermal degradation of AzoPTCD occurs at 675 °C. The growth of the PVD films was establi

Kinetics of photoinduced birefringence in the guest-host system of poly(methyl methacrylate) doped with azobenzene-containing crown ethers

The kinetics of the buildup and decay of photoinduced birefringence was examined in a series of host-guest systems: azobenzene-containing crown ethers, differing in the size of the crowns, dissolved in a poly (methyl methacrylate) matrix. In all samples, the kinetics of the buildup of the birefringence was reasonably described by a sum of two exponential functions, the time constants being inverse

A comparison of DSM-IV-TR and DSM-5 diagnostic criteria for gambling disorder in a large clinical sample

Background and aims: Gambling-related crimes are known to be associated with gambling disorder (GD). Due to a lack of consensus in the scientific community regarding the relevance of this diagnostic criterion, it was removed from the DSM-5. The primary aim of this study was to investigate through structural equation modeling (SEM) whether higher GD severity in treatment-seeking GD patients with a

Unreported exclusion and sampling bias in interpretation of randomized controlled trials in patients with STEMI

Aims: To assess the impact of sampling bias due to reported as well as unreported exclusion of the target population in a multi-center randomized controlled trial (RCT)of ST-elevation myocardial infarction (STEMI). Methods and Results: We compared clinical characteristics and mortality between participants in the DANAMI-3 trial to contemporary non-participants with STEMI using unselected registrie

Bioreduction

Bioreduction has emerged over the years as an alternative method to organic synthesis for the generation of chiral precursors of commercial interest. Bioreductions operate under mild conditions of pH and temperature with the help of highly regio- and enantio-selective oxidoreductase enzymes.In this contribution, the different oxidoreductase families involved in bioreductions are exemplified and th

METHOD FOR PROVIDING AN AGGREGATE OF ALIGNED NANOWIRES AT A LIQUID-LIQUID INTERFACE

A method for forming an aggregate of assembled aligned nanowires (20), wherein said nanowires comprise an elongate wire portion (21) and a head portion (23) at a first end of the elongate wire portion, comprising providing a fluid comprising a first liquid (11), a second liquid (12) and a plurality of nanowires, wherein the first and second liquids phase separate into a first phase, a second phase

Low-Pressure MWPC System for the detection of Alpha-Particles and Fission Fragments

A low-pressure, position-sensitive, multi-wire proportional chamber (LPMWPC) system with an active area 12×12 cm 2 for the detection of heavy nuclear fragments, has been developed for use in tagged photon beam experiments. The LPMWPC system can be operated in single as well as double step operational modes. In the case of double step operational mode with a high gas amplification factor, signals f

Suppression of acoustic streaming by the inhomogeneity-induced acoustic body force

Rayleigh streaming in a homogeneous fluid has been extensively studied, and plays an important role in the manipulation of particles in microscale acoustofluidics. In this work, the acoustic streaming is investigated in a glass-silicon microchannel as it evolves in fluids made inhomogeneous in density and compressibility (or speed of sound) by the addition of solute molecules. It is found that the

Cross Sections and Rosenbluth Separations in 1H(e,e'K+)Lambda up to Q2=2.35 GeV2

The kaon electroproduction reaction 1H(e,e′K+)Λ was studied as a function of the virtual-photon four-momentum, Q2, total energy, W, and momentum transfer, t, for different values of the virtual-photon polarization parameter. Data were taken at electron beam energies ranging from 3.40 to 5.75 GeV. The center of mass cross section was determined for twenty-one kinematics corresponding to Q2 of 1.90

Twin-scroll turbocharger turbine stage evaluation of experimental data and simulations

In this study a novel comparison of CFD, measured data and a ID-model is presented for a Twin-scroll turbocharger turbine stage. Both full and single admission flow divisions were taken into consideration and shown to represent "on-engine" conditions in the high and low engine rpm range respectively for a heavy-duty 6-cylinder diesel engine. With this in mind, the turbine stage was evaluated for e

(e,e'p) reaction at true quasielastic kinematics in 16O, 12C, and 208Pb at JLab

The reactions 16O(e,e'p) 15N, 208Pb(e,e'p) 207Tl and 12C(e,e'p) 11B were measured in experiments E00-102 and E06-007 performed at JLab (VA, USA) at true quasielastic kinematics (xB = 1) with constant energy (ω) and momentum (q) transferred over a wide pmiss range. These experiments address several open issues in nuclear structure such as the role of relativity and of long-range correlations in the

The MAX IV imaging concept

The MAX IV Laboratory is currently the synchrotron X-ray source with the beam of highest brilliance. Four imaging beamlines are in construction or in the project phase. Their common characteristic will be the high acquisition rates of phase-enhanced images. This high data flow will be managed at the local computing cluster jointly with the Swedish National Computing Infrastructure. A common image

The Coherent Bremsstrahlung Beam at MAX-lab Facility

The linearly polarized photon beam for photonuclear researches has been produced at MAX-lab facility on the base of coherent bremsstrahlung process of electrons in a diamond crystal. Test experiments have been performed at electron energies 143.9 and 192.7 MeV with a diamond crystal 0.1 mm thick. The measured coherent bremsstrahlung spectra demonstrate typical features to be observed at higher ele

Radiation Spectra of 200 MeV Electrons in Diamond and Silicon Crystals at Axial and Planar Orientations

Results of the first experiment on studying the radiation spectra of electrons with energy 192 7 MeV in diamond and silicon crystals at axial and plane orientation performed at the MAX-lab facility were presented. At these orientation the particle's motion can be both regular, when axial and planar channeling are possible, and chaotic, when the coherent electron interaction with single strings rev