Insights into Early Hydration of Portland Limestone Cement from Infrared Spectroscopy and Isothermal Calorimetry
Isothermal calorimetry and diffuse reflectance infrared DR–FTIR spectroscopy are combined to correlate evolutions of spectroscopic signatures with rates of chemical reactions as reflected in the rate of heat emitted during the first 38 h of cement hydration. Portland limestone cement mortar is employed and the analysis is repeated for two different mixing procedures. Intensive blender mixing with