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The lowest-lying doublet electronic states of CoC - A theoretical study

Multiconfigurational SCF and second-order perturbation theory have been employed to study seven low-lying electronic states of the CoC molecule (X-2 Sigma(+), A(2)Delta, B(2)Phi, C(2)Phi, D(2)Pi, E(2)Pi, and F(2)Sigma(+)). Three doublet electronic states have been described for the first time: B 2 (D C(2)Phi (R-0 = 1.617 angstrom, To = 10455 cm(-1). and a), = 1159 cm(-1)), and D(2)Pi (R-0 = 1.632

Biodiversity at Linnaeus birthplace in the parish of Stenbrohult, southern Sweden. 1. Habitat distribution of red-listed species.

The habitat distribution of red-listed plants, fungi and animals that have been found in the central parts of the parish of Stenbrohult, southern Sweden since 1970 is presented (Tables 1-4). In the centre of the 5 000 ha study area Carl Linnaeus was born in 1707, and he spent his summers there until 1727. In 1971-2002 at least 183 red-listed species have been found, with 73 wood-living beetle spec

Shell-model Influence in the Rotational Nucleus 86Mo

High-spin states in Mo-86 were studied by means of the fusion evaporation reaction Ni-58(S-32,2p2n) Mo-86 at 135 MeV beam energy. Charged-particle-gamma gamma and -gamma gamma gamma coincidences recorded with the early implementation of the GAMMASPHERE array and the MICROBALL charged-particle detection system were used to largely extend the level scheme of the T-tau=1 nucleus Mo-86 to a possible s

Cholescintigraphy: a valuable diagnostic method in acute cholecystitis

In 91 patients (36 men, 55 women) who were hospitalized with symptoms of acute cholecystitis, cholescintigraphy was performed with 99m-Tc-ethyl-IDA, in order to evaluate the method in the diagnosis of acute inflammatory disease of the gallbladder. Five groups of patients were recognized: (A) abnormal scintigraphy and verified gallbladder disease, (B) abnormal scintigraphy without verified gallblad

Ion conducting electrolytes based on aggregating comblike poly(propylene oxide)

Solid and gel electrolytes based on comblike poly(propylene oxide) (PPO) have been prepared and studied. The polymer consisted of a polyethylene backbone densely grafted with PPO side chains terminated by hexadecanoyl chain ends. Analysis by impedance spectroscopy of the solid polymer electrolytes containing lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) salt showed ion conductivities of 10(-5

Public relations and tourism: Critical reflections and a research agenda

This article is based on the belief that research focused on PR tourism is of fundamental importance to understanding the role of PR in contemporary culture. Our analysis shows that tourism has not received much attention from PR researchers and that a critical perspective uncovers a host of key issues in promotional culture: power, politics and diplomacy in international communication; risk, ethi

Beyond Newtonian thinking – towards a non-linear archaeology : applying chaos theory to archaeology

In this article the authors suggest that chaos theory can provide us witha new perspective on archaeology. Newtonian thinking is predominantin archaeology, as well as in the humanities in general. This results inthe hegemony of analytic methods and a linear way of thinking on causeand effect. However, chaos theory has shown that behind many phen-omena that may seem random lies order. Since these c

Synthesis of podoscyphic acid

Podoscyphic acid 1, a fungal metabolite inhibiting RNA-directed DNA polymerises, was synthesised in four steps starting from dodecanal. The concluding ester hydrolysis of 4 was not feasible with chemical reagents, only enzymatic hydrolysis was mild enough to release the highly reactive natural product in good yields. (C) 2002 Elsevier Science Ltd. All rights reserved.

Clinical pharmacology of thalidomide

Background: Thalidomide has a chiral centre, and the racemate of (R)- and (S)-thalidomide was introduced as a sedative drug in the late 1950s. In 1961, it was withdrawn due to teratogenicity and neuropathy. There is now a growing clinical interest in thalidomide due to its unique anti-inflammatory and immunomodulatory effects. Objective: To critically review pharmacokinetic studies and briefly rev

Association testing of the protein tyrosine phosphatase 1B gene (PTPN1) with type 2 diabetes in 7,883 people

Protein tyrosine phosphatase (PTP)-1B, encoded by the PTPN1 gene, inactivates the insulin signal transduction cascade by dephosphorylating phosphotyrosine residues in insulin signaling molecules. Due to its chromosomal location under a chromosome 20 linkage peak and the metabolic effects of its absence in knockout mice, it is a candidate gene for type 2 diabetes. Recent studies have associated com

Distributed Clocking and Clock Generation in Digital CMOS SoC ASICs

With shrinking technologies and higher clock rates comes the possibility to transform multi chip implementations to a single System on Chip (SoC). Implementing clock distribution and limiting the power consumption becomes increasingly troublesome with increased clock rate and chip area. Therefore, designing large Systems on Chip makes it necessary to search for new implementation methods. In this

Liquid chromatography-mass spectrometry analysis of enzyme-hydrolysed carboxymethylcellulose for investigation of enzyme selectivity and substituent pattern

A series of celloendoglucanases: Bacillus agaradhaerens Cel 5a, Humicola insolens Cel 5a, H. insolens Cel 7b, H. insolens Cel 45a, Trichoderma reesei Cel 7b, and T reesei Cel 45a were used to hydrolyse carboxymethylcellulose (CMC) and the hydrolysis products were investigated with a novel liquid chromatography-mass spectrometry (LC-MS) method. Separation was achieved using a graphitised carbon chr